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Chemical Accident Prevention
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112(r) Regulated Flammable Substances
112(r) Regulated Flammable Substances
Chemical Name
CAS #
Threshold Quantity (lbs)
Basis for Listing
Acetaldehyde
75-07-0
10,000
g
Acetylene [Ethyne]
74-86-2
10,000
f
Bromotrifluorethylene [Ethene, bromotrifluoro-]
598-73-2
10,000
f
1,3-Butadiene
106-99-0
10,000
f
Butane
106-97-8
10,000
f
1-Butene
106-98-9
10,000
f
2-Butene
107-01-7
10,000
f
Butene
25167-67-3
10,000
f
2-Butene-cis
590-18-1
10,000
f
2-Butene-trans [2-Butene, (E)]
624-64-6
10,000
f
Carbon oxysulfide [Carbon oxide sulfide (COS)]
463-58-1
10,000
f
Chlorine monoxide [Chlorine oxide]
7791-21-1
10,000
f
2-Chloropropylene [1-Propene, 2-chloro-]
557-98-2
10,000
g
1-Chloropropylene [1-Propene, 1-chloro-]
590-21-6
10,000
g
Cyanogen [Ethanedinitrile]
460-19-5
10,000
f
Cyclopropane
75-19-4
10,000
f
Dichlorosilane [Silane, dichloro-]
4109-96-0
10,000
f
Difluoroethane [Ethane, 1,1-difluoro-]
75-37-6
10,000
f
Dimethylamine [Methanamine, N-methyl-]
124-40-3
10,000
f
2,2-Dimethylpropane [Propane, 2,2-dimethyl-]
463-82-1
10,000
f
Ethane
74-84-0
10,000
f
Ethyl acetylene [1-Butyne]
107-00-6
10,000
f
Ethylamine [Ethanamine]
75-04-7
10,000
f
Ethyl chloride [Ethane, chloro-]
75-00-3
10,000
f
Ethylene [Ethene]
74-85-1
10,000
f
Ethyl ether [Ethane, 1,1'-oxybis-]
60-29-7
10,000
g
Ethyl mercaptan [Ethanethiol]
75-08-1
10,000
g
Ethyl nitrite [Nitrous acid, ethyl ester]
109-95-5
10,000
f
Hydrogen
1333-74-0
10,000
f
Isobutane [Propane, 2-methyl]
75-28-5
10,000
f
Isopentane [Butane, 2-methyl-]
78-78-4
10,000
g
Isoprene [1,3-Butadiene, 2-methyl-]
78-79-5
10,000
g
Isopropylamine [2-Propanamine]
75-31-0
10,000
g
Isopropyl chloride [Propane, 2-chloro-]
75-29-6
10,000
g
Methane
74-82-8
10,000
f
Methylamine [Methanamine]
74-89-5
10,000
f
3-Methyl-1-butene
563-45-1
10,000
f
2-Methyl-1-butene
563-46-2
10,000
g
Methyl ether [Methane, oxybis-]
115-10-6
10,000
f
Methyl formate [Formic acid, methyl ester]
107-31-3
10,000
g
2-Methylpropene [1-Propene, 2-methyl-]
115-11-7
10,000
f
1,3-Pentadiene
504-60-9
10,000
f
Pentane
109-66-0
10,000
g
1-Pentene
109-67-1
10,000
g
2-Pentene, (E)-
646-04-8
10,000
g
2-Pentene, (Z)-
627-20-3
10,000
g
Propadiene [1,2-Propadiene]
463-49-0
10,000
f
Propane
74-98-6
10,000
f
Propylene [1-Propene]
115-07-1
10,000
f
Propyne [1-Propyne]
74-99-7
10,000
f
Silane
7803-62-5
10,000
f
Tetrafluoroethylene [Ethene, tetrafluoro-]
116-14-3
10,000
f
Tetramethylsilane [Silane, tetramethyl-]
75-76-3
10,000
g
Trichlorosilane [Silane, trichloro-]
10025-78-2
10,000
g
Trifluorochloroethylene [Ethene, chlorotrifluoro-]
79-38-9
10,000
f
Trimethylamine [Methanamine, N,N-dimethyl-]
75-50-3
10,000
f
Vinyl acetylene [1-Buten-3-yne]
689-97-4
10,000
f
Vinyl chloride [Ethene, chloro-]
75-01-4
10,000
a, f
Vinyl ethyl ether [Ethene, ethoxy-]
109-92-2
10,000
g
Vinyl fluoride [Ethene, fluoro-]
75-02-5
10,000
f
Vinylidene chloride [Ethene, 1,1-dichloro-]
75-35-4
10,000
g
Vinylidene fluoride [Ethene, 1,1-difluoro-]
75-38-7
10,000
f
Vinyl methyl ether [Ethene, methoxy-]
107-25-5
10,000
f
Basis for Listing:
Mandated for listing by Congress
On EHS list, vapor pressure 10 mmHg or greater
Toxic gas
Toxicity of hydrogen chloride, potential to release hydrogen chloride, & history of accidents
Toxicity of sulfur trioxide and sulfuric acid, potential to release sulfur trioxide, & history of accidents
Flammable gas
Volatile flammable liquid
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